期刊
MOLECULES
卷 26, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/molecules26051475
关键词
tautomerism; proton transfer; excited-state; spectroscopy
资金
- Bulgarian National Science Fund within The National Science Program VIHREN, Project T-Motors [KP-06-DV-9]
Excited-state intramolecular proton transfer (ESIPT) has become an attractive research field with various aspects such as excitation wavelength dependence, anti-Kasha ESIPT, fast and slow ESIPT, reversibility and irreversibility, hydrogen bonding, and geometrical factors. Studies also involve excited-state double proton transfer (ESDPT) mechanisms including concerted and stepwise processes.
In this short review, we attempt to unfold various aspects of excited-state intramolecular proton transfer (ESIPT) from the studies that are available up to date. Since Weller's discovery of ESIPT in salicylic acid (SA) and its derivative methyl salicylate (MS), numerous studies have emerged on the topic and it has become an attractive field of research because of its manifold applications. Here, we discuss some critical aspects of ESIPT and tautomerization from the mechanistic viewpoint. We address excitation wavelength dependence, anti-Kasha ESIPT, fast and slow ESIPT, reversibility and irreversibility of ESIPT, hydrogen bonding and geometrical factors, excited-state double proton transfer (ESDPT), concerted and stepwise ESDPT.
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