4.6 Article

Synthesis and Structural Characterization of a Silver(I) Pyrazolato Coordination Polymer

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Summary: Experimental multinuclear determination of chemical shifts, especially N-15 and Ag-109, of five silver(I) trinuclear pyrazolate complexes, (PzAg)(3), coupled with ZORA and GIAO calculations, provided new insights into these compounds. A comprehensive collection of spin-spin coupling constants was measured for the first time for some of these compounds, and the absence of aromaticity in (PzAg)(3) was concluded based on NICS and ACID analyses.

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