期刊
MATERIALS RESEARCH BULLETIN
卷 134, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2020.111062
关键词
Niobium oxide; Spore carbon; Lithium ion batteries; High power; Anode
资金
- Science and Technology Program of Taizhou [14GY03]
- Excellent Young Scientists Fund of Taizhou University [2017JQ004]
A facile solvothermal method was proposed to combine aspergillus oryzae spore carbon (ASC) with niobium oxide, forming ASC/Nb2O5 composite material with homogeneously decorated Nb2O5 nanoparticles. The composite material exhibited superior electrochemical performance, with discharge capacities of 189 and 65 mA h g(-1) as the current density increased from 0.2 C to 20 C. Additionally, good long-time cycling span was achieved with a retention of 50.8% at 5 C after 1200 cycles.
Herein, we propose a facile solvothermal (ST) method to combine aspergillus oryzae spore carbon (ASC) with niobium oxide to form ASC/Nb2O5 composite material. Nb2O5 nanoparticles are homogeneously decorated on the surface of ASC with wrinkled secondary architecture, which provides an interconnected network for fast electron/ion transportation. Impressively, positive advantages including fast reaction kinetics, large specific surface area & porosity and enhanced structural stability are acquired in the well-designed ASC/Nb2O5 composite. Consequently, superior electrochemical performance is obtained for the designed ASC/Nb2O5 electrode, which delivers discharge capacities of 189 and 65 mA h g(-1) as the current density increases from 0.2 C to 20 C. Moreover, good long-time cycling span is further convinced for the ASC/Nb2O5 electrode with retention of 50.8% at 5 C after 1200 cycles. Our research paves the road for synthesis of advanced high-power electrodes for energy storage devices.
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