期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 143, 期 11, 页码 4100-4105出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c13286
关键词
-
资金
- Carbon to X Project [2020M3H7A1098283]
- National Research Foundation (NRF) - Ministry of Science and ICT, Republic of Korea [2020R1A2C2004310]
- National Research Foundation of Korea [2020R1A2C2004310] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
This study achieved the functionalization of azide-alkyne click-based microporous organic polymer (CMOP), generating mesoionic carbene species in hollow CMOP (H-CMOP) and forming H-CMOP-Rh, which exhibited excellent heterogeneous catalytic performance in the stereoselective polymerization of arylacetylenes.
This work reports the functionalization of azide-alkyne click-based microporous organic polymer (CMOP). The generation of triazolium salts and successive deprotonation induced mesoionic carbene species in hollow CMOP (H-CMOP). Rh(I) species could be coordinated to the mesoionic carbene species to form H-CMOP-Rh, showing excellent heterogeneous catalytic performance in the stereoselective polymerization of arylacetylenes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据