期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 104, 期 7, 页码 3130-3138出版社
WILEY
DOI: 10.1111/jace.17710
关键词
evaporation; first principle simulation; SiO2 glass; transition metal oxides
资金
- Innovation Talent Promotion Plan of Shaanxi Province for Science and Technology Innovation Team [2020TD-003]
- National Natural Science Foundation of China [51521061, 51572223]
- China Postdoctoral Science Foundation [2019M660265]
- Creative Research Foundation of Science and Technology on Thermostructural Composite Materials Laboratory (NWPU) [5150200033]
Among transition metal oxides, Nb2O5 and Ta2O5 reduce the evaporation of SiO2, while TiO2, ZrO2, and HfO2 help decrease the evaporation of SiO2 glass. The SiO2-HfO2 sample has the least evaporation.
To investigate the effect of transition metal oxides on the evaporation characteristic of SiO2 glass at 1700 degrees C, nine transition metal oxides were added to SiO2 glass. The results show that V2O5, MoO3, and WO3 have little effect on the high-temperature stability of SiO2 glass due to their evaporation at 1500-1700 degrees C. Besides, Nb2O5 and Ta2O5 reduce the evaporation of SiO2 by covering the surface of the sample. Moreover, by improving the content of cristobalite, the evaporation of the SiO2-Cr2O3 sample decreases. Meanwhile, TiO2, ZrO2, and HfO2 are beneficial to decreasing the evaporation of SiO2 glass because Ti, Zr, and Hf diffuse into c-SiO2. Meanwhile, the SiO2-HfO2 sample possesses the least evaporation.
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