期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 12, 期 5, 页码 1390-1395出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.0c03356
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资金
- Bundesministerium fur Bildung und Forschung within the Verbundforschung funding scheme [05K16RG1, 05K16GUC, 05K19RG3, 05K19GU3]
- Deutsche Forschungsgemeinschaft [Mu 1068/22, Schi 378/12, SFB925/A3]
The core level photoionization of the ionic molecular radical HF+ was studied using the photon-ion merged-beams technique, revealing complex ultrafast dissociation dynamics of the F is core hole excited sigma* state. Electronic structure calculations attributed this complex process to a spin-dependent dissociation of the excited sigma* biradical state.
The F is core level photoionization of the ionic molecular radical HF+ has been studied using the photon-ion merged-beams technique at a synchrotron radiation source. Upon analyzing kinetic energy release (KER) dependent photoion yield spectra, complex ultrafast dissociation dynamics of the F is core hole excited sigma* state can be revealed. By means of configuration-interaction electronic structure calculations of the excited molecular potential energy curves, this complex process can be attributed to a spin-dependent dissociation of the excited sigma* biradical state.
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