期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 5, 页码 4290-4295出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c02825
关键词
-
资金
- JSPS KAKENHI [20H02725, 18K05076, 19K05422]
- Ogasawara Toshiaki Memorial Foundation
- Grants-in-Aid for Scientific Research [20H02725, 19K05422] Funding Source: KAKEN
A new compound HPHAC 2 was synthesized, exhibiting reversible oxidation behavior, and its crystal structures and formation of a complex with C-60 were revealed. Spectroscopic analyses were performed based on magnetic circular dichroism and theoretical calculations.
Radially pi-extended hexapyrrolohexaazacoronene (HPHAC 2) was synthesized in two steps with 2,5-di-tert-butyl-acenaphtho[1,2-c]pyrrole and hexafluorobenzene. Like its parent HPHAC 1a, 2 exhibited reversible oxidation behavior. Crystal structures of not only the neutral and dicationic compounds but also the radical cation were all revealed. While analyzing its peculiar structure, the formation of a 1:1 complex with C-60 was observed in solution by NMR and absorption analyses. The spectroscopic analyses of 2 and la were performed based on magnetic circular dichroism and theoretical calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据