4.7 Article

Rapid synthesis of dual-mesoporous silica aerogel with excellent adsorption capacity and ultra-low thermal conductivity

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JOURNAL OF NON-CRYSTALLINE SOLIDS
卷 555, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.jnoncrysol.2020.120547

关键词

Silica aerogel; Dual-mesoporous; Oil-in-water emulsion; Thermal property; Ambient pressure drying

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In this study, a dual-mesoporous silica aerogel was synthesized using MTES and TEOS as precursors, demonstrating unique structure and excellent properties. The aerogel can efficiently separate oil contaminants from surfactant-stabilized emulsions, while also exhibiting outstanding hydrophobicity and sorption capacity.
In this paper, using methyltriethoxysilane (MTES) and tetraethoxysilane (TEOS) as co-precursor, dual-mesoporous silica aerogel was rapidly prepared within 20 h by ambient pressure drying. The dual-mesoporous structure can be obtained just by control the amount of TEOS. The skeleton structure of the dual-mesoporous aerogel is composed of small mesopores (3-6 nm) and large mesopores (17-30 nm). Moreover, the thermal conductivity (as low as 0.0223 W/(mK)) of the dual-mesoporous aerogel is much lower than most of MTES-based aerogels. More importantly, the obtained dual-mesoporous aerogel can separate oil from surfactant-stabilized oilin-water emulsion, the separation efficiency as high as 97.6%. In addition, the aerogel exhibits superhydrophobic with a contact angle of 157.4 degrees, thermally stable reaching up to 489.5 degrees C and outstanding sorption capacity reaching up to 8.4-17.1 g/g. The dual-mesoporous silica aerogel have potential application in thermal insulating and organic pollutants sorption.

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