期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1225, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2020.129076
关键词
Formylation; Acylation; Amines; Palladium; Nano zeolite; Clinoptilolite
The novel palladium nanoparticles stabilized by clinoptilolite as a natural zeolite showed good to excellent yields in N-formylation and N-acylation of amines at room temperature. The catalyst, easily recovered and reused for 7 consecutive runs without loss in activity, was characterized structurally and morphologically using XRD, FT-IR, BET, and TEM techniques.
Novel palladium nanoparticles stabilized by clinoptilolite as a natural inexpensive zeolite prepared and used for N-formylation and N-acylation of amines at room temperature at environmentally benign reaction conditions in good to excellent yields. Pd (II) was immobilized on the surface of clinoptilolite via facile multi-step amine functionalization to obtain a sustainable, recoverable, and highly active nanocatalyst. The structural and morphological characterizations of the catalyst carried out using XRD, FT-IR, BET and TEM techniques. Moreover, the catalyst is easily recovered using simple filtration and reused for 7 consecutive runs without any loss in activity. (C) 2020 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据