期刊
JOURNAL OF MOLECULAR LIQUIDS
卷 325, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molliq.2020.114677
关键词
N-hydroxyphthalimide; Solubility; Hansen solubility parameter; Thermodynamic properties
资金
- Science and technology project of Henan province [182102210002]
- Key Research Projects of Henan Higher Education Institutions [19A530004]
This study reported the equilibrium solubility and thermodynamic properties of NHPI in various solvents. The solubility of NHPI was found to increase with temperature, with the highest solubility observed in 2-methoxyethanol. The solubility of NHPI in different solvents is influenced by multiple factors, and the mixing and dissolution processes were determined to be entropy-driven and spontaneous.
The equilibrium solubility and thermodynamic properties of N-hydroxyphthalimide (NHPI) in n-propanol, 2-methoxyethanol, 1 ,4-dioxane, n-propyl acetate, ethanol, acetonitrile, methyl acetate, 2-ethoxyethanol, acetone, methanol and ethyl acetate were reported. Solubility determinations were performed through laser monitoring method in the temperature range of (278.15-323.15) K (except 1.4-dioxane at 288.15-323.15 K). It is found that the mole fraction solubility of NHPI increases apparently with augmented experimental temperature. The measured data is observed highest in 2-methoxyethanol (0.3807), followed by 2-ethoxyethanol (0.2601), 1,4-dioxane (0.2307), acetone (0.1260), methanol (0.06572), ethanol (0.06138), methyl acetate (0.05282), n-propanol (0.04670), acetonitrile (0.04141), ethyl acetate (0.03992), n-propyl acetate (0.03286) at T - 298.15 K. Various properties of materials including solvent polarity and Hansen solubility parameter of NHPI as well as selected solvents were summarized to analyze the solubility order of NHPI in studied solvents. The analysis consequence shows that solubility of NHPI in selected solvents is affected by multiple factors. Moreover, all recorded solubility was regressed by the modified Apleblat equation, Wilson model, NRTL model and NRTL-SAC model, attaining the average 100ARD (average relative deviation) value lower than 1.200 and average 10(4)RMSD (root-mean square deviation) value lower than 1.550. Furthermore, analysis of thermodynamic properties indicates that the mixing and dissolution of NHPI in all considered cases are entropy-driven and spontaneous processes. (C) 2020 Published by Elsevier B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据