期刊
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
卷 529, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jmmm.2021.167871
关键词
Landau model; Magnetocaloric materials; First-order magnetic transition; Second-order magnetic transition
The field exponent for the magnetic entropy change was evaluated using the Landau model, providing classification for ferromagnetic-to-paramagnetic transitions in magnetocaloric materials. The transition can be categorized as a first-order magnetic transition, a second-order magnetic transition, or a critical point at the border between the two. The influence of the magnetic field on the transition temperature was found to be weak for the SOMT and follows a power law for the CP and FOMT.
The field exponent for the magnetic entropy change n = dln(vertical bar Delta S vertical bar)/dln(H) in a magnetic field was evaluated using the Landau model to provide a classification for the nature of the ferromagnetic-to-paramagnetic transitions at the Curie temperature T-C in magnetocaloric materials. The magnetic phase transition can be classified as a first-order magnetic transition (FOMT), a second-order magnetic transition (SOMT) or a critical point (CP) at the border between the first and second order transitions. The value of n is mapped as a function of the reduced temperature and the reduced magnetic field for the FOMT, SOMT and CP. The influence of the magnetic field on the transition temperature was found to be relatively weak for the SOMT and corresponds to a power law for the CP and FOMT.
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