Visual colorimetric detection of ammonia under gaseous and aqueous state: Approach on cesium lead bromide perovskite-loaded porous electrospun nanofibers

In this work, we fabricate porous cesium lead bromide nanofibers (CsPbBr3 NFs) via electrospinning and employ them in a sensor to effectively detect both gaseous and aqueous ammonia. The CsPbBr3 NFs are produced by first mixing cesium lead bromide nanocrystals (CsPbBr3 NCs) with polystyrene (PS), followed by solidifying the mixture into NFs using electrospinning. Porous NFs are modified using the volatile solvent toluene, which is volatilized during the electrospinning process. The applicability of the proposed CsPbBr3 NFs for use under various environmental conditions is verified by analyzing their stability in response to changes in temperature, moisture level and pH, which are critical drawbacks of CsPbBr3 NCs. Gaseous ammonia (9 mg L-1) in an N-2 carrier is subsequently detected using the photoluminescence (PL) properties of the CsPbBr3 NFs. In addition, an ammonia concentration of 100.0 mg L-1 in an aqueous solution can be detected using the PL intensity. Therefore, we believe that the proposed CsPbBr3 NFs show significant promise for use in detection sensors to assess the extent of food decay, allowing customers to purchase fresh agricultural products more safely. (C) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

Automated summary

Porous cesium lead bromide nanofibers were fabricated via electrospinning and utilized in a sensor to detect gaseous and aqueous ammonia effectively. The stability of the nanofibers under different environmental conditions was verified, showing significant promise in assessing food decay for safe purchase of fresh agricultural products.