期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 885, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2021.115100
关键词
Hydrogen peroxide; Glucose; Electrochemical sensor
资金
- National Natural Science Foundation of China [21575002, 61671019]
- Natural Science Foundation from the Bureau of Education of Anhui Province [KJ2019A0073]
CuGa2O4 nanoparticles were synthesized using hydrothermal-calcination technique and exhibited significant electrocatalytic effects for the reduction of H2O2 and oxidation of glucose. Under optimal conditions, sensitive detection of H2O2 and glucose was achieved, showing linear changes in concentration with electrochemical signals. This promising nanoparticle could improve non-enzymatic glucose sensors.
In this paper, spinel-type CuGa2O4 nanoparticles were synthesized by hydrothermal-calcination technique, and were characterized by X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive spectrometer (EDS). The electrochemical behaviors of CuGa2O4 nanoparticles modified glassy carbon electrode (CuGa2O4/GCE) under neutral condition with H2O2 and alkaline condition with glucose were studied. It was found that CuGa2O4 nanoparticles exhibited apparent electrocatalytical effects for the reduction of H2O2 and the oxidation of glucose. As a result, cyclic voltammetric and chronoamperometric techniques could be used in the sensitive detection of H2O2 and glucose. Under the optimal condition, the concentration of H2O2 varied linearly with the electrochemical signal in the range of 5?200 ?M, and the detection limit was 5 ?M (S/N = 3), while glucose showed a linear change in the range of 0.05?2 mM, and the detection limit was 25 ?M (S/N = 3). The modified electrode had good repeatability and stability, and showed a promising application in the detection of actual samples. The outstanding electrochemical performance make this spinel CuGa2O4 nanoparticle promising for the improvement of non-enzymatic glucose sensor.
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