期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 882, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2021.114990
关键词
Acetaminophen; Dopamine; Pseudo-reference electrode; Silver-based nanoporous structure; Electrochemical sensor
资金
- National Natural Science Foundation of China [51271205, 50801070, 51571093]
- Excellent Young College Teacher Development Program in Guangdong Province [Yq2013006]
- Research and Application of Key Technologies Oriented the Industrial Development [90035-3283309, 90035-3283321]
- Project of Science and Technology Plan by Guangzhou city [2013Y2-00102]
- Chinese Central Authority University Fund [2015ZM094, 16lgjc6]
- National Nature Science Foundation of China [21622509, 21475122, 21527806]
- Department of Science and Techniques of Jilin Province [20160201008GX]
- Jilin Province Development and Reform Commission [2016C014, 2017C053-1]
- Science and Technology Bureau of Changchun [15SS05]
This paper presents a novel two-step facile strategy for fabricating nanoporous Ag and nanoporous Ag/AgCl materials to simplify manufacturing procedure and optimize experiment conditions. The fabricated NP-Ag electrodes show promising current response for AC and DA, while NP-Ag/AgCl electrodes exhibit enhanced stability and miniature size as micro-size reference electrodes. Overall, the innovative surface modification of the synthesized materials has positive implications for massive production and point-of-care testing applications.
In this paper, a novel two-step facile strategy was first proposed to fabricate nanoporous Ag (NP-Ag) and nanoporous Ag/AgCl (NP-Ag/AgCl) materials to simplify manufacturing procedure, shorten processing time, and optimize experiment condition. Co-electrodeposition of AgSn alloy on the interdigital gold electrode (IGE) and subsequent electrochemical dealloying in HCl solution by applying different potentials. The surface morphologies as well as the electrochemical characterizations of the fabricated NP-Ag and NP-Ag/AgCl IGEs were investigated. The fabricated NP-Ag IGEs were evaluated as biomolecules simultaneous electrochemical sensors for determination of acetaminophen (AC) and dopamine (DA). In addition, the performance of the fabricated NP-Ag/AgCl IGEs, as micro-size reference electrodes, were studied. The NP-Ag electrodes were found promising linear current response to AC (correlation coefficient, R2 = 0.9906) and DA (correlation coefficient, R2 = 0.9961), under the concentration ranges from 0.5 to 290 mu M and 0.25 to 500 mu M, respectively. Moreover, the fabricated NP-Ag/AgCl IGEs were possessed of enhanced stability and miniature size as pseudo-reference electrodes (p-REs) in contrast with commercial p-REs, which benefiting from abundant ion-exchange sites and quantities of nanochannels on the sponge-like surface. Results demonstrated the innovative surface modification of as-synthesized NP-Ag and NP-Ag/AgCl have positive implication for massive production of nanoporous Ag-based materials and the utilization of prospective point-of-care testing.
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