4.4 Article

Highly strained Ge1-xSnx alloy films with high Sn compositions grown by MBE

期刊

JOURNAL OF CRYSTAL GROWTH
卷 557, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.jcrysgro.2020.125996

关键词

Ge1-xSnx alloy; Molecular beam epitaxy; Strain; Bandgap

资金

  1. National Key R&D Program of China [2018YF.A200, 2017YFA0303702]
  2. National Natural Science Foundation of China [51732006, 11890702, 51721001, 51702153]
  3. Jiangsu Entrepreneurship and Innovation Program

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The study found that Ge1-xSnx alloy films are highly strained even after Sn segregation, and increasing the Sn composition shrinks the bandgap of Ge1-xSnx. Low growth temperatures and high growth rates are beneficial for achieving higher Sn compositions, while strain plays an important role in limiting Sn incorporation.
We have grown a series of Ge1-xSnx films with high Sn compositions up to 16.6% directly on Ge (100) substrates using molecular beam epitaxy (MBE). Reciprocal space mapping (RSM) study shows that all the Ge1-xSnx alloy films are highly strained even after Sn segregation has occurred. Ellipsometry measurements confirm that increasing the Sn composition shrinks the bandgap of Ge1-xSnx. We have found that low growth temperatures and high growth rates are beneficial to achieve higher Sn compositions, and strain is an important role in limiting the Sn incorporation.

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