期刊
JOURNAL OF CLEANER PRODUCTION
卷 290, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2020.125184
关键词
Tender coconut husks; Deep eutectic solvent; Cellulose nanocrystals; Biodegradable plastic; Lignocellulose biorefinery
资金
- Council of Scientific and Industrial Research (CSIR), India
The production of cellulose reinforced bio-composites offers a sustainable alternative to petroleum-based plastics, while utilizing waste agro-industrial residues for lignocellulose biorefinery can help combat environmental pollution. Research shows that using deep eutectic solvents to extract lignin, functionalize cellulose into nanocrystals, and use them as bio-fillers can lead to the successful production of bioplastic films with excellent mechanical and moisture barrier properties.
The production of cellulose reinforced bio-composites has emerged as an efficient bio-sustainable alternative for high-quality functional polymeric materials to replace the presently dominated petroleum-based plastics. Also because, lignocellulose biorefinery from waste agro-industrial residues has attracted widespread attention for combating increasing environmental pollution caused by incineration of such wastes. In this prospect, the fractionation of tender coconut husks (TCH) to yield cellulose, hemicellulose and lignin fractions has been investigated by different pretreatment methodologies using conventional and novel reaction media. Excellent outcomes were obtained with the use of the deep eutectic solvent composed of choline chloride and oxalic acid dihydrate that led to the dissolution of 95.5% of the initial lignin in TCH to yield a cellulose fractional recovery of 87.5% at the optimal conditions attained by parametric variations. Interestingly, the same eutectic mixture also functionalized the obtained cellulose to cellulose nanocrystals (CNC) with 69% yield, crystallinity index of 88.6% and average particle size of 146 nm. Further, isolated starch from waste tamarind seeds was used as the polymer matrix wherein the CNC was added as a suitable bio-filler to cast bioplastic films using biodiesel byproduct glycerol as a plasticizer. The characterization of the biodegradable films revealed a tensile strength of 21.8 MPa along with outstanding thermal and moisture barrier properties. The results elucidate that the huge dependence for petro-plastics could be reduced with the integrated valorization of solid wastes that can aid wide-ranging industries and align with the rising motto of a bioeconomy. (c) 2020 Elsevier Ltd. All rights reserved.
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