期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 854, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157096
关键词
One-pot synthesis; CuZnInSe3 nanocrystals; Tetrahedra; Bandgap optimization; Solar cells material
资金
- Cultivation Fund of Changchun University of Chinese Medicine [2018KJ18]
This study demonstrates the synthesis of quaternary CuZnInSe3 (CZISe) nanocrystals using a simple one-pot approach, suitable for large scale device applications, with unique tetrahedral shape. The CZISe NCs exhibit strong electronic absorption, potentially making them excellent absorbers for thin film solar cells.
Quaternary CuZnInSe3 (CZISe) nanocrystals (NCs) have been synthesized using a facile one-pot approach, which are suitable for large scale device applications. This synthesis was assisted with oleylaminde (OLA) as ligand for stabilization and shape control as well as dodecanethiol (DDT) for balancing the reactivity of metal precursors. The CZISe NCs crystallize in the zinc blende structure with unique tetrahedral shape that can potentially enhance interaction and facilitate charge transfer between NCs. The NCs show strong electronic absorption in the UV and visible regions and significant absorption in the near-infrared (NIR). A direct bandgap around 1.30 eV, inferred from the UV-Vis spectrum, suggests that the NCs can be an excellent absorber for thin film solar cells. Prototype solar cells fabricated from these CZISe NC films show a power conversion efficiency of 0.77% under standard AM1.5 illumination. This study demonstrates a new, simple and ecofriendly method to synthesize CZISe NCs with tetrahedral shape potentially useful for solar cell applications. (C) 2020 Elsevier B.V. All rights reserved.
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