期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 871, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.159157
关键词
Aerogel; Electrode material; Iron oxide; Polyaniline; Halloysite
资金
- National Natural Science Foundation of China [51772202]
- Natural Science Foundation of Tianjin City [18JCQNJC03000]
In this work, a three-dimensional hybrid aerogel HGA-PANI loaded with Fe3O4 was fabricated, showing promising electrical properties and structural stability.
Great progress had been made in the synthesis and application of graphene, graphene oxide (GO) aerogels, and reduced graphene oxide (rGO). However, most of the reported graphene hybrid aerogels reduced the mechanical properties of the obtained materials because of their wide pore size distribution, which limited the recycling of aerogels. Therefore, it was urgent to prepare graphene hybrid aerogels with uniform mesopores or micropores to enhance the structural stability of aerogels. Meanwhile, the mechanical and electrical properties of graphene hybrid aerogels could be further improved. In this paper, halloysite/ graphene-polyaniline three-dimensional hybrid aerogel loaded with Fe3O4(HGA-PANI) was fabricated. The microstructure, mechanical properties, and electrochemical properties of HGA-PANI were characterized by scanning electron microscope (SEM), X-ray Photoelectron Spectroscopy (XPS), N-2 adsorption-desorption tests, universal material testing machine, electrochemical workstation, and so on. Halloysite nanotubes (HNT) were fixed on the surface of graphene sheets or intercalated between graphene nanosheets. The three-dimensional network structure was formed, which reduced the agglomeration between graphene sheets. The hybrid of HNT and graphene sheet increased the graphene's specific surface area and constructed a three-dimensional network porous structure. Through Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD), Electrochemical impedance spectroscopy (EIS), and cycle stability tests, HGA-PANI had acceptable electrical properties, large capacitance, thin internal resistance, and amazing cyclical stability. (C) 2021 Elsevier B.V. All rights reserved.
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