Self-Cleaning-Mediated SERS Chip Coupled Chemometric Algorithms for Detection and Photocatalytic Degradation of Pesticides in Food

Pesticide residues in food have been a grave concern to consumers. Herein, we have developed a dual-mode SERS chip using Cu2O mesoporous spheres decorated with Ag nanoparticles (MCu2O@Ag NPs) as both sensing and degradation/clearing unit for rapid detection of pymetrozine and thiram pesticides in tea samples. Three kinds of chemometric algorithms were comparatively applied to analyze the collected SERS spectra of pesticides. In comparison, random frog-partial least squares achieved the best performance with root mean square error of prediction and residual predictive deviation values of 0.9871, 6.17, and 0.9873, 6.64 for pymetrozine and thiram, respectively. Additionally, the prepared SERS chip showed great photocatalytic activity to degrade pesticides under visible light irradiation. Through a facile method, this work presented a novel dual-functional SERS chip for the rapid detection and degradation of low-concentration pesticides in both environmental and food samples.

Automated summary

This study developed a dual-functional SERS chip for rapid detection and degradation of pesticides in tea samples, utilizing Cu2O mesoporous spheres decorated with Ag nanoparticles. Three chemometric algorithms were compared for pesticide analysis, with random frog-partial least squares showing the best performance. The prepared SERS chip also exhibited strong photocatalytic activity for pesticide degradation under visible light irradiation.