Synthesis of Au/UiO-66-NH2/Graphene composites as efficient visible-light photocatalysts to convert CO2

The production of new solar fuel through CO2 photocatalytic reduction has aroused tremendous attention in recent years because of the increased demand of global energy sources and global warming caused by the mass concentration of CO2 in the earth's atmosphere. In this work, UiO-66-NH2 was co-modified by the Au nanoparticles (Au-NPs) and Graphene (GR). The resultant nanocomposite exhibits a strong absorption edge in visible light owing to the surface plasmon resonance (SPR) of Au-NPs. More attractively, Au/UiO66-NH2/GR displays much higher photocatalytic activity (49.9 mmol) and selectivity (80.9%) than that of UiO-66-NH2/GR (selectivity: 71.6%) and pure UiO-66-NH2 (selectivity: 38.3%) for the CO2 reduction under visible light. The enhanced photocatalytic performance is primarily dued to the surface plasmon resonance (SPR) of Au-NPs, which could enhance the visible light absorption. The GR sheets could play as an electron acceptor with superior conductivity and thus suppress the recombination of electrons and holes. Besides, the GR could also improve the dispersibility of UiO-66-NH2 so as to expose more active sites and strengthen the capture of CO2. The contact effect and synergy effect among different samples are strengthened in the ternary composites and the photocatalytic performance is therefore improved. This study demonstrates a MOF based hybrid composite for efficient photocatalytic CO2 reduction, the findings not only prove great potential for the design and application of MOFs-based materials but also bring light to novel chances in the development of new high performance photocatalysts. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Automated summary

The UiO-66-NH2 composite modified by Au nanoparticles and graphene shows enhanced photocatalytic activity and selectivity for CO2 reduction under visible light. This improvement is mainly due to the surface plasmon resonance of Au nanoparticles and the electron-accepting and dispersing effects of graphene.