4.5 Article

Effect of pyrolysis temperature on pyrolysis of pine saw dust and application of bio-char

出版社

SPRINGER
DOI: 10.1007/s13762-021-03159-8

关键词

Pine saw dust; Pyrolysis; Pyrolysis product; Bio-char; Ag+

资金

  1. Specialized Research Fund for the National Natural Science Foundation of China [21966019]
  2. Yunan Ten Thousand Talents Plan Young & Elite Talents Project [2018-73]
  3. Yunnan Ten Thousand Talents Plan Industrial Technology Talents Project [2019-1096]

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The pyrolysis of pine saw dust at varying temperatures affects the characteristics and potential uses of the resulting bio-gas, bio-oil, and bio-char. Higher pyrolysis temperatures lead to increased bio-gas yield, decreased bio-char yield, and relatively stable bio-oil yield. The bio-gas exhibits high combustible gas content and heating value at higher temperatures, while the main identified compounds in bio-oil offer potential applications in various industries.
Pine saw dust as a typical forest residue is slowly pyrolyzed at 400-800 degrees C in a fixed bed system. The influence of pyrolysis temperature on the characteristics of bio-gas, bio-oil and bio-char is investigated and then to assess their potential uses. The result indicates that the yield of bio-gas increases as pyrolysis temperature increases, while the yield of bio-char decreases. The pyrolysis temperature does not have much effect on the yield of bio-oil. The bio-gas has high content of combustible gases (H-2 + CO) and heating value with increase in pyrolysis temperature. The highest content of combustible gases is 76.96% with the highest heating value of 16.46 MJ/Nm(3). The main identified compounds of bio-oil are the furfuran, alkane and phenol, respectively. Therefore, bio-oil can be used as the potential chemical materials in the food, chemical, pharmaceutical and other industries. The physiochemical properties of bio-char such as element content, and BET specific surface area have changed as pyrolysis temperature increases. Besides, bio-char could be potentially applied not only to remove Ag+ from aqueous solutions but also to produce a new value-added nanocomposite.

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