期刊
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
卷 16, 期 3, 页码 -出版社
ESG
DOI: 10.20964/2021.03.08
关键词
carboxymethyl cellulose; biosourced polymer electrolytes; magnesium acetate; electrical studies
资金
- Centre of Research and Instrument Management, Universiti Kebangsaan Malaysia [MI-2019-018]
- Malaysia's Ministry of Education through the Fundamental Research Grant Scheme [FRGS/1/2019/TK10/UKM/02/1]
Biodegradable-carboxymethyl cellulose (CMC) extracted from empty fruit bunches of palm oil is used to produce biopolymer electrolytes in combination with magnesium acetate, achieving a high ionic conductivity at ambient temperature. The biosourced polymer electrolytes demonstrate good electrochemical stability and ion conduction ability, showing promise as a potential alternative to lithium batteries.
As demands for global lithium supplies have raised questions about the sustainability of the supply of lithium, a potential alternative to lithium batteries has been developed. New biodegradable-carboxymethyl cellulose (CMC) extracted from empty fruit bunches of palm oil is used to produce biopolymer electrolytes (BPE) using magnesium acetate salt. Solution casting has been used to prepare biopolymer electrolytes in various ratios of magnesium acetate. Via Fourier transform infrared characterisation, electrochemical impedance spectroscopy, transference number measurements and linear sweep voltammetry, studies on the structural, electrical and electrochemical behaviour of CMC were conducted. Upon the addition of 20 wt% of magnesium acetate, the highest ionic conductivity of 1.83 x 10(-3 )S cm(-1) at ambient temperature was achieved. The interactions between CMC and magnesium acetate were verified by the Fourier transform infrared results. Electrochemical stability of more than 2 V was shown by the biosourced polymer electrolytes, whereas the measurement of transference number showed that electrolytic conduction was dominated by ions.
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