期刊
ENERGY
卷 99, 期 -, 页码 103-114出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2016.01.042
关键词
Spillover mechanism; Redox replacement; Hydrogen storage; Graphene; Layered double hydroxides
资金
- Iran National Science Foundation
- National Elites Foundation
New efficient hydrogen storage hybrids were fabricated based on hydrogen spillover mechanism, including chemisorptions and dissociation of H-2 on the surface of LDH (layered double hydroxides) and diffusion of H to rGO (reduced graphene oxide). The structures and compositions of all of the hybrids (LDHs/rGO) have been verified using different methods including transmission electron microscopy, X ray diffraction spectroscopy, infrared spectroscopy and Brunauer-Emmett-Teller analysis. Then, the abilities of the LDHs/rGOs, as hydrogen spillover, were investigated by electrochemical methods. In addition, the LDHs/rGOs were decorated with palladium, using redox replacement process, and their hydrogen spillover properties were studied. The results showed that the hydrogen adsorption/desorption kinetics, hydrogen storage capacities and stabilities of (PdLDH)-L-#/rGOs are better than Pd/rGO. Finally presence of different polymers (synthesis with monomers, 4-aminophenol, 4-aminothiophenol, o-phenylenediamine and p-phenylenediamine) at the surface of the Pd#LDH/rGOs on hydrogen storage were studied. The results showed that presence of o-phenylenediamine and p-phenylenediamine improves the kinetics of the hydrogen adsorption/desorption and increase the capacity of the hydrogen storage. (C) 2016 Elsevier Ltd. All rights reserved.
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