Synthesis and characterization of flame-retardant rigid polyurethane foams derived from gutter oil biodiesel

In this study, gutter oil biodiesel-based polyols (GOBP) and a reactive-type flame retardant named diethyl bis(2-hydroxyethyl)-aminomethylphosphonate (BHAPE) were both synthesized. Subsequently, gutter oil biodiesel-based flame-retardant rigid polyurethane foams (BPUFs) were prepared with GOBP, BHAPE, aluminum hydroxide (an additive-type flame retardant) and polymeric diphenylmethane diisocyanate. The properties of the BPUFs, including density, thermal conductivity, compressive properties, chemical component, morphology, thermal stability, limiting oxygen index, cone calorimetry testing, char residues stability were characterized. Among them, BPUF-AB owning 6.97 wt% of GOBP, 18.59 wt% of BHAPE and 39.77 wt% of aluminum hydroxide obtained a lower density of 0.097 g/cm(3), a lower thermal conduction of 0.048 W/(m * k) and the highest compressive strength of 187 +/- 13 kPa. Fire testing revealed a highest limiting oxygen index value of 30.1% and passed the UL-94 standard test. Cone calorimetry testing revealed that the peak heat release rate and peak smoke production release of BPUF-AB were reduced by 51.08% and 57.10%, respectively. Meanwhile, the total heat release rate and total smoke production were respectively decreased by 36.88% and 40.79%. The results indicate that BPUFs derived from gutter oil biodiesel are prosperously potential biomaterials with good thermal stability for fire insulation porous materials in future architecture applications.

Automated summary

The study successfully synthesized gutter oil biodiesel-based polyols (GOBP) and a reactive-type flame retardant named diethyl bis(2-hydroxyethyl)-aminomethylphosphonate (BHAPE), and prepared flame-retardant rigid polyurethane foams (BPUFs) using these materials. The BPUFs showed promising properties such as low density, low thermal conductivity, high compressive strength, good flame retardancy, and thermal stability, making them potential biomaterials for fire insulation porous materials in future architecture applications.