期刊
ELECTROCHIMICA ACTA
卷 369, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2020.137641
关键词
Layer of Ni microspheres; LTIM-Pt-electrode; TDM-Pt-electrode; DSCs
资金
- National Natural Science Foundation of China [21875173]
- Fundamental Research Funds for the Central Universities of China [2042018kf0238, 2042019gf0028]
- Science and Technology Planning Project of Hubei Provincial Market Supervision Administration [Hbscjg-kj201921]
The study utilized chemical bath deposition to coat nickel microspheres on frosted glass as conductive substrates, followed by the deposition of a thin Pt layer using low-temperature immersion method and thermal decomposition method to obtain Pt/Ni/glass electrodes for dye-sensitized solar cells (DSCs). Results showed that the well-optimized LTIM-electrode achieved a significant increase in fill factor and power conversion efficiency for the DSC device.
Several hundred Ni microspheres with a diameter of 2-3 mu m coated on frosted glass by chemical bath deposition are used as conductive substrates. Then, low-temperature immersion method (LTIM) and thermal decomposition method (TDM) are adopted respectively to deposit a thin Pt layer on Ni/glass and obtain Pt/Ni/glass electrodes which were employed as counter electrodes (CEs) for dye-sensitized solar cells (DSCs). The results show that the DSC device with well-optimized LTIM-electrode achieves a remarkable increase of 0.69 and 7.78% in fill factor (FF) and power conversion efficiency (PCE) respectively. However, well-optimized TDM-electrode and traditional sputtered-Pt-electrode demonstrate an efficiency of 6.59% and 7.55% with a FF of 0.65 and 0.69, respectively. In addition, the LTIM-electrode has the lowest Pt loading of only 15.4 mu g/cm(2) among these three types of CEs. Thus, LTIM presents here paved the way for the preparation of excellent electrocatalytic CEs with extremely low Pt loading on F-doped SnO2 (FTO) free of Ni/glass substrates in DSCs, greatly reducing the cost of present photovoltaic devices. Furthermore, this LTIM can be applied to deposit other noble metals on a variety of flexible substrates, including polyethylene naphthalate or terephthalate. (C) 2020 Elsevier Ltd. All rights reserved.
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