4.7 Article

Novel functionalized indigo derivatives for organic electronics

期刊

DYES AND PIGMENTS
卷 186, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2020.108966

关键词

Indigo; Indigoids; Organic field effect transistors; Semiconductors; OFET

资金

  1. Ministry of Science and Higher Education of the Russian Federation [075-15-2020-779]

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A series of novel indigo derivatives were synthesized and investigated as semiconductor materials in organic field-effect transistors, with different structures showing significant impact on charge transport properties. The results of this study will be important for the rational design of a new generation of indigo-based semiconductors.
A series of nine novel indigo derivatives, including diiodoindigo, octahalogenated indigoids and compounds with extended pi-conjugated system, were synthesized, characterized and investigated as semiconductor materials in organic field-effect transistors (OFETs). Among them, 6,6 '-diiodoindigo demonstrated the ambipolar behavior with balanced p-type and n-type mobilities. The complete substitution of hydrogens at the indigo core with halogen atoms led to low electron mobilities in OFETs. An extension of the conjugated system through the introduction of small aromatic substituents (thiophene and phenyl) resulted in predominant p-type behavior. Fusion of aromatic rings resulted in z-shaped dibenzoindigo, which showed poor charge transport properties due to the non-optimal arrangement of molecules along each other in the crystal lattice. The acquired data fulfilled the previously reported model based on the relationship between the chemical nature of substituents and their positions at the indigo core, optoelectronic properties of materials and their performance in OFETs. The results of this study will be useful for rational design of a new generation of the indigo-based semiconductors for biocompatible organic electronics.

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