期刊
CRYSTAL GROWTH & DESIGN
卷 21, 期 3, 页码 1727-1733出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.0c01626
关键词
-
资金
- Goran Gustafsson prize by the Royal Swedish Academy of Science
- U.S. Department of Energy Basic Energy Sciences, Heavy Elements program [DE-SC0019220]
- Vetenskapsradet [2020-04437, 2018202000233]
- U.S. Department of Energy (DOE) [DE-SC0019220] Funding Source: U.S. Department of Energy (DOE)
- Swedish Research Council [2020-04437] Funding Source: Swedish Research Council
The crystal structure of this metal-organic material consists of planar inorganic layers interconnected by organic linkers to form a three-dimensional framework with a Kagome topology, which has not been previously recognized in f-element coordination chemistry.
The metal-organic material (UO)-O-V((UO2)-O-VI)(2)(OH)(5)-(Triaz)(2) (Triaz = 1,2,4-triazolate) has been isolated from the reaction of UO2(NO3)(2)center dot 6H(2)O with 1,2,4-triazole in the ionic liquid 1-ethyl-3-methylimidazolium acetate ([C(2)mim][OAc]). The compound's crystal structure is comprised of planar inorganic layers interconnected by organic linkers into a 3D framework. These layers represent a uranium-based coordination polymer with a Kagome topology that to the best of our knowledge has never been recognized in f-element coordination chemistry.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
