期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 611, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.colsurfa.2020.125860
关键词
Layered double hydroxide; Clay mineral; Point of zero net charge; Structural charge
资金
- National Natural Science Foundation of China [21872082, 21573133]
- Natural Science Foundation of Shandong Province of China [ZR2019MB025]
A new ESEN model was proposed to predict the PZNC of amphoteric solids, taking into account structural charge and using easily available characteristic physical constants. The model was validated with data from (hydr)oxides, LDHs, and silicate clay minerals, showing acceptable feasibility and accuracy. This is the first feasible model to predict the PZNC of both LDHs and silicate clay minerals, which is important for the design synthesis and application of new materials.
Many models such as electrostatic, crystallographic, and electronegativity models have been developed to predict the point of zero net charge (PZNC) of (hydr)oxides without structural charge. Nevertheless, there is still a lack of feasible models to predict the PZNC of structurally charged amphoteric solids, such as positively charged layered double hydroxides (LDHs) and negatively charged clay minerals, using easily available characteristic physical constants. Herein, a new model, called general electrostatic-electronegativity (ESEN) model, was proposed based on the classical electrostatic and electronegativity models by taking into account the structural charge (sigma(st)). The new model correlates the PZNC of amphoteric solids with sigma(st) and easily available characteristic physical constants (ionic valence, ionic radius, and electronegativity). The empirical parameters in the model were simulated using the PZNC data of 22 (hydr)oxides previously reported. The so-obtained ESEN model equations can predict the PZNC of (hydr)oxides, LDHs, and silicate clay minerals with acceptable feasibility and accuracy. To the best of our knowledge, this is the first feasible model to predict the PZNC of both LDHs and silicate clay minerals using easily available characteristic physical constants, which is important for the design synthesis and application of new materials.
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