Effect of load-cycling amplitude on performance degradation for proton exchange membrane fuel cell

Durability is one of the critical issues to restrict the commercialization of proton exchange membrane fuel cells (PEMFCs) for the vehicle application. The practical dynamic operation significantly affects the PEMFCs durability by corroding its key components. In this work, the degradation behavior of a single PEMFC has been investigated under a simulated automotive load-cycling operation, with the aim of revealing the effect of load amplitude (0.8 and 0.2 A/cm(2) amplitude for the current density range of 0.1-0.9 and 0.1-0.3 A/cm(2), respectively) on its performance degradation. A more severe degradation on the fuel cell performance is observed under a higher load amplitude of 0.8 A/cm(2) cycling operation, with-10.5% decrease of cell voltage at a current density of 1.0 A/cm(2). The larger loss of fuel cell performance under the higher load amplitude test is mainly due to the frequent fluctuation of a wider potential cycling. Physicochemical characterizations analyses indicate that the Pt nanoparticles in cathodic catalyst layer grow faster with a higher increase extent of particle size under this circumstance because of their repeated oxidation/reduction and subsequent dissolution/agglomeration process, resulting in the degradation of platinum catalyst and thus the cell performance. Additionally, the detected microstructure change of the cathodic catalyst layer also contributes to the performance failure that causes a distinct increase in mass transfer resistance. (C) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

Automated summary

Under simulated automotive load-cycling operation, higher load amplitude leads to more severe degradation of fuel cell performance, mainly due to the faster growth of Pt nanoparticles in the cathodic catalyst layer and resulting degradation of the catalyst. Additionally, detected microstructure changes in the cathodic catalyst layer contribute to performance failure.