Parent and alkylated polycyclic aromatic hydrocarbons in surface sediments of mangrove wetlands across Taiwan Strait, China: Characteristics, sources and ecological risk assessment

The characteristics, distributions and sources of parent polycyclic aromatic hydrocarbons (PAHs) and alkyl-PAHs (A-PAHs) as well as their ecological risk were explored in six mangrove wetlands across the Taiwan Strait, China. A-PAHs fingerprinting information, combined with PAHs diagnostic ratios and a positive matrix factorization model, were used to identify the sources of PAHs in the mangrove wetland surface sediment samples. The results showed that the total concentration of the 36 PAHs in the sediment samples varied from 186.2 to 2469.2 ngg(-1). Furthermore, the total concentration of PAHs would be underestimated about 37.1%-80.6% when only the concentrations of 16 priority PAHs were examined in the sediment samples. Coal combustion (32.7%) and petroleum combustion (24.6%) were identified as important contributing sources in the Yunxiao, Fugong, and Quanzhou mangrove wetlands, whereas the main source was mainly petroleum combustion (49.1%) in the Guandu, Zhuwei and Waziwei mangrove wetlands. In addition, the guidelines for assessing the ecological risk of individual A-PAHs need to be developed due to lack of criteria for most individual A-PAHs. (C) 2020 Elsevier Ltd. All rights reserved.

Automated summary

This study explored the characteristics, distributions, sources, and ecological risk of parent PAHs and A-PAHs in six mangrove wetlands across the Taiwan Strait in China. The total concentration of 36 PAHs in sediment samples varied greatly, with coal combustion and petroleum combustion identified as important contributing sources in some wetlands. Individual ecological risk assessments of A-PAHs are needed due to lack of criteria for most of them.