A spectrophotometric method for measuring permanganate index (CODMn) by N,N-diethyl-p-phenylenediamine (DPD)

A new spectrophotometric method for measuring permanganate index (chemical oxygen demand using potassium permanganate (KMnO4) as oxidant, CODMn) in water was established. The method was based on the rapid oxidation of N,N-diethyl-p-phenylenediamine (DPD) by residual KMnO4 in digestion solution under neutral pH condition to form the stable pink radical (DPD center dot+). Only 20 s were enough to form the pink DPD center dot+. The generated DPD center dot+ could be quantitatively measured by a visible spectrophotometer at 551 nm. Stoichiometric coefficient of the reaction between KMnO4 and DPD was close to 1:5 (1:5.07). There was a well linear relationship (R-2 = 0.999) between the change of the absorbance of DPD center dot+ at 551 nm and the concentration of CODMn in the range of 0-4.46 mg L-1. Limit of detection of the DPD method was as low as 0.02 mg L-1 CODMn. The DPD method was highly accurate for measuring CODMn in standard solutions with well recovery rates of 99.17%-102.22%, and was well tolerant to the interference of coexistent Cl- and Fe3+. The DPD method was successfully applied for measuring CODMn in real water samples, including surface water, underground water and drinking water. In comparison to the traditional titration method, the proposed DPD method was more convenient to operate, required less samples and digestion reagents (i.e., KMnO4 and H2SO4) and could be employed for online monitor. (C) 2020 Elsevier Ltd. All rights reserved.

Automated summary

A new spectrophotometric method for measuring permanganate index in water was established, which showed high sensitivity, convenience in operation, and tolerance to interfering substances.