期刊
CHEMICAL ENGINEERING JOURNAL
卷 406, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.126875
关键词
Asymmetric supercapacitor; Fe2O3-based anode; Surface pseudocapacitance; Spatial-confining strategy; Long-term cycling stability
资金
- National Natural Science Foundation of China [51772138, 51572118, 51601082, 11974150]
- Fundamental Research Funds for the Central Universities [lzujbky-2020-59]
A physical spatial-confining strategy is proposed to enhance the electrochemical performance of Fe2O3-based electrode by introducing Al2O3 nanograins on the surface, resulting in a significant improvement in important electrochemical performance and long-term cycling stability.
Developing an anode with outstanding electrochemical properties remains a significant challenge in building high-performance asymmetric supercapacitor devices. The promising Fe2O3-based anode shows exceptional theoretical electrochemical performance but limited by its undesired practical energy density and long-term cycling stability. Herein, we propose a physical spatial-confining strategy to enhance the electrochemical performance of the Fe2O3-based electrode with tunable surface pseudocapacitance using redox electrolyte Na2SO3. By introducing Al2O3 nanograins on the surface of Fe2O3, electrolyte Na+ can diffuse through the surface-anchored Al2O3 nanograin but SO32- was physically blocked due to the Na+ ions fast diffusion nature of Al2O3 during the electrochemical operations. And a positive charge center by Na+ was formed on the side of Fe2O3, which attracts SO32- securing a stable bridge between the dissociative SO32- groups and electrode. Such a physically constrained structure ensures the fast dual-ion-involved redox reactions, leading to a significant electrochemical performance (including capacitance performance and long-term cycling stability). The Al2O3/Fe2O3-based anode delivers a high capacitance of 2371F g(-1) at 5 mV s(-1) with a capacitance retention of 1277F g(-1) even at 200 mV s(-1), which also shows superior cycling stability of 95.38% after 5000 cycles. A novel dual-electrolyte Al2O3/Fe2O3@CNTs/Na2SO3//MnO2@CNTs/Na2SO4 asymmetric supercapacitor device with a potential window of 0-2.2 V was configured, which shows the remarkable performance of energy density of 174 W h kg(-1) at a power density of 4492 W kg(-1).
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