A Tubular g-C3N4 Based Composite Photocatalyst Combined with Co3O4 Nanoparticles for Photocatalytic Degradation of Diesel Oil

The photocatalysis is a very promising technique to address the serious issues of environmental pollution. Among the common photocatalysts, the graphitic carbon nitride (g-C3N4) is widely used for the photodegradation of organic pollutants due to its proper band structure. To further improve the photocatalytic performance of g-C3N4, a novel composite photocatalyst of Co3O4/PT-C3N4 has been prepared by using a one-pot calcination method, in which cobalt tetroxide (Co3O4) nanoparticles as the cocatalyst are introduced on the surface of rectangular hollow g-C3N4 substrate (PT-Co3O4). As a result, the obtained composite photocatalyst (Co3O(4)/PT-C3N4) delivers an excellent photodegradation performance for diesel oil under a simulated sunlight, which can improve the separation efficiency of the photo-induced electron-hole pairs. The Co3O4/PT-C3N4 composite photocatalyst exhibits a high degradation efficiency of 96.27% after 2 h of visible light, which is much higher than that of the PT-C3N4 photocatalyst. Moreover, the composite photocatalyst can still maintain a high photodegradation efficiency after 10 cycles, exhibiting an excellent cyclic stability. The photo-induced carriers generated by the Co3O4/PT-C3N4 composite photocatalyst follow the Z-scheme heterojunction transfer mechanism. This work gives a fresh idea for the exploration of new high-performance photocatalyst for the treatment of organic environmental pollutants. [GRAPHICS] .

Automated summary

The composite photocatalyst of graphitic carbon nitride and cobalt tetroxide exhibits excellent photodegradation performance for organic pollutants, providing a new possibility for the treatment of environmental pollution.