4.5 Article

Pd/C-Catalyzed H2 Evolution from Tetrahydroxydiboron Hydrolysis

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CATALYSIS LETTERS
卷 151, 期 10, 页码 3004-3010

出版社

SPRINGER
DOI: 10.1007/s10562-021-03547-2

关键词

Pd/c; Tetrahydroxydiboron; H-2 evolution; Tandem reaction; Kinetic isotope effect

资金

  1. National Natural Science Foundation of China [21805166]
  2. 111 Project [D20015]
  3. Engineering Research Center of Eco-environment in Three Gorges Reservoir Region, Ministry of Education, China Three Gorges University [KF2019-05]
  4. outstanding young and middle-aged science and technology innovation teams, Ministry of Education, Hubei province, China [T2020004]

向作者/读者索取更多资源

The production of hydrogen from non-fossil sources is a key research challenge. Recent studies have shown that aqueous solutions of tetrahydroxydiboron can serve as a hydrogen source, with commercial and inexpensive Pd/C as an efficient and recyclable catalyst for hydrogen evolution.
The production of H-2 from non-fossil sources is a key research challenge to contributing solving the forthcoming energy problem. Aqueous solutions of tetrahydroxydiboron have very recently appeared as a H-2 source, from which both hydrogen atoms are provided by water, in the presence of highly sophisticated nanocatalysts. Herein, commercial and cheap Pd/C is shown to be an efficient and recyclable catalyst for H-2 evolution upon tetrahydroxydiboron hydrolysis. Graphic

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