期刊
BIORESOURCE TECHNOLOGY
卷 324, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2020.124614
关键词
Solid acid catalyst; Biomass carbon; Sargassum horneri; Esterification; Biodiesel
资金
- College of Chemical Engineering, Zhejiang University of Technology
The solid acid catalyst prepared by sulfonated Sargassum horneri carbon efficiently catalyzes the esterification reaction of oleic acid and methanol for biodiesel preparation. By optimizing the conditions, the conversion rate of oleic acid can reach 96.4%, and the catalyst can still maintain a high conversion rate after four cycles of use.
A solid acid catalyst prepared by sulfonated Sargassum horneri carbon was utilized for the esterification reaction of oleic acid and methanol. The formed amorphous carbon layers during carbonization and the access of sulfonic acid groups during sulfonation can catalyze the esterification reaction for biodiesel preparation efficiently. The catalyst was characterized by various methods to investigate its physical and chemical properties. With carbonization at 300 degrees C for 2 h followed by sulfonation at 90 degrees C for 5 h, the catalyst reached acid density of 1.40 mmol/g. The catalyst dosage, methanol/oleic acid (molar ratio), reaction temperature, and reaction time were optimized to 10 wt%, 15:1, 70 degrees C, and 3 h, respectively. Under the optimal condition, the conversion of oleic acid reached 96.4%. Additionally, the catalyst was regenerated after four cycles, with the conversion of oleic acid still reaching 95.4%.
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