期刊
BIOMACROMOLECULES
卷 22, 期 4, 页码 1399-1405出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.biomac.0c01625
关键词
cellulose degradation; nanocellulose; order/disorder transitions; atomic force microscopy
资金
- Academy of Finland [300364]
- Business Finland [42,472/31/2020]
- Academy of Finland (AKA) [300364, 300364] Funding Source: Academy of Finland (AKA)
The process of cellulose hydrolysis involves an intermediate semi-fibrous stage before forming objects resembling cellulose nanocrystals in a solid/gas system. The length of these nanocrystal-like objects is well correlated with molar mass and X-ray diffraction shows a slight increase in crystallinity index as hydrolysis proceeds. This research provides a modern visual complement to over a century of cellulose degradation studies.
Cellulose hydrolysis is an extensively studied process due to its relevance in the fields of biofuels, chemicals production, and renewable nanomaterials. However, the direct visualization of the process accompanied with detailed scaling has not been reported because of the vast morphological alterations occurring in cellulosic fibers in typical heterogeneous (solid/liquid) hydrolytic systems. Here, we overcome this distraction by exposing hardwood cellulose nanofibers (CNFs) deposited on silica substrates to pressurized HCl gas in a solid/gas system and examine the changes in individual CNFs by atomic force microscopy (AFM). The results revealed that hydrolysis proceeds via an intermediate semi-fibrous stage before objects reminiscent of cellulose nanocrystals were formed. The length of the nanocrystal-like objects correlated well with molar mass, as analyzed by gel permeation chromatography, performed on CNF aerogels hydrolyzed under identical conditions. Meanwhile, X-ray diffraction showed a slight increase in crystallinity index as the hydrolysis proceeded. The results provide a modern visual complement to >100 years of research in cellulose degradation.
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