期刊
APPLIED CLAY SCIENCE
卷 203, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.clay.2021.106006
关键词
Layered double hydroxide; Epoxide-driven alkalization; Solid base catalyst; Nanoparticle; Transesterification
资金
- JSPS KAKENHI [JP18K19134, JP20H02442]
- JSPS-CNRS bilateral program
In this study, nano Li-Al LDH was synthesized and transformed into Li-Al MMO, showing high specific surface area and abundant strong basic sites. Compared to samples prepared by co-precipitation method, LiAl MMO exhibited higher catalytic activity due to the larger amount of active sites.
Li-Al layered double hydroxide (LDH) and LDH-derived mixed metal oxide (MMO) are promising solid base catalysts due to their instinct and strong surface basicity. Herein, nano Li-Al LDH was synthesized via the crystal growth from metal hydroxide nanoseeds with low crystallinities. The present Li-Al LDH possesses high specific surface area (326 m2 g-1), highly crystalline, and high purity. The present nano LDH undergoes a transformation to Li-Al MMO with a high specific surface area (349 m2 g-1) of abundant strong basic sites. Indeed, the present LiAl MMO exhibits an enhanced catalytic activity for a transesterification reaction between methanol and soybean oil compared to one prepared through a co-precipitation method, thanks to the larger amount of active sites.
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