Elemental mercury removal by I--doped Bi2WO6 with remarkable visible-light-driven photocatalytic oxidation

In this work, I--doped Bi2WO6 composites were synthesized using a one-step hydrothermal method, and the effect of iodine doping on their photocatalytic efficiency in gas-phase elemental mercury removal was evaluated under visible-light irradiation. The results showed that 1.0 wt.% iodine doped Bi2WO6 exhibited the optimal Hg-0 removal efficiency of 87.6 % and 97.5 % under N-2+O-2+CO2 and N-2+O-2+CO2+SO2+NO conditions, respectively. The improved photocatalytic activity of Bi2WO6 can be ascribed to the reduction in the potential energy of its conduction band and recombination rate of electron-hole pairs, as well as the acceleration of charge transfer. The density functional theory calculations showed that iodine was doped in the (WO4)(2-) layer and oxidized HgO can be adsorbed on the surface of I- doped Bi2WO6. The OBi site was found to be exhibit weak adsorption with respect to HgO, implying that most conducive to the desorption of HgO. Finally, the photocatalysis mechanisms was elaborated.

Automated summary

In this study, iodine-doped Bi2WO6 composites were synthesized through a one-step hydrothermal method to evaluate their photocatalytic efficiency in gas-phase elemental mercury removal under visible-light irradiation. The results showed that 1.0 wt.% iodine-doped Bi2WO6 exhibited the optimal Hg-0 removal efficiency due to reduced potential energy in the conduction band, decreased recombination rate of electron-hole pairs, and accelerated charge transfer. The density functional theory calculations suggested that iodine doping occurred in the (WO4)(2-) layer, facilitating the adsorption of oxidized HgO on the surface of the doped Bi2WO6.