期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 24, 页码 13343-13349出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202100337
关键词
corrosion; electrochemical dissolution; passivation; transition metals; stability
资金
- project CREATE by European Union's Horizon 2020 research and innovation programme [721065]
- Deutsche Forschungsgemeinschaft [CH 1763/5-1]
- National Science Foundation (NSF) through the NSF CAREER award [CBET-1941204]
- Projekt DEAL
Current research focuses on finding cheaper transition metals to replace expensive noble metals as electrocatalyst materials, utilizing activity descriptors for identifying highly active electrocatalysts and establishing periodic correlations to support the design of more stable electrocatalysts.
Extensive research efforts are currently dedicated to the search for new electrocatalyst materials in which expensive and rare noble metals are replaced with cheaper and more abundant transition metals. Recently, numerous alloys, oxides, and composites with such metals have been identified as highly active electrocatalysts through the use of high-throughput screening methods with the help of activity descriptors. Up to this point, stability has lacked such descriptors. Hence, we elucidate the role of intrinsic metal/oxide properties on the corrosion behavior of representative 3d, 4d, and 5d transition metals. Electrochemical dissolution of nine transition metals is quantified using online inductively coupled plasma mass spectrometry (ICP-MS). Based on the obtained dissolution data in alkaline and acidic media, we establish clear periodic correlations between the amount of dissolved metal, the cohesive energy of the metal atoms (E-coh), and the energy of oxygen adsorption on the metal (Delta H-O,H-ads). Such correlations can support the knowledge-driven search for more stable electrocatalysts.
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