期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 17, 页码 9290-9295出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202100295
关键词
aromaticity; BN compounds; boron; isoelectronic analogues; polycycles
资金
- German Research Foundation (DFG) [HE 6171/7-1, 401738081, HE 6171/6-1 (401739196)]
- Projekt DEAL
Access to dithiophene-fused oxadiborepins and the first azadiborepins via a modular synthesis route has been achieved. These new compounds emit intense blue light, some demonstrating fluorescence quantum yields close to unity. The weak aromatic character of the novel 1,2,7-azadiborepin ring was demonstrated through in-depth theoretical investigations using nucleus-independent chemical shift (NICS) scans and anisotropy of the induced current density (ACID) calculations.
Access to dithiophene-fused oxadiborepins and the first azadiborepins attained via a modular synthesis route are presented. The new compounds emit intense blue light, some of which demonstrate fluorescence quantum yields close to unity. Cyclic voltammetry (CV) revealed electrochemically reversible one-electron reduction processes. The weak aromatic character of the novel 1,2,7-azadiborepin ring is demonstrated with in-depth theoretical investigations using nucleus-independent chemical shift (NICS) scans and anisotropy of the induced current density (ACID) calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据