期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 21, 页码 12001-12006出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202100507
关键词
2D materials; lanthanides; luminescence; magnetic properties; van der Waals interactions
资金
- Spanish Ministry of Science and Innovation [PGC2018-098630-B-I00, PGC2018-093863-B-C21, MAT2017-83468-R]
- Spanish Structures of Excellence Maria de Maeztu program [MDM-2017-0767]
This study reported the microwave assisted synthesis of a bidimensional (2D) metal–organic framework (MOF). The material exhibits single-ion magnet behavior and can be exfoliated into stable nanosheets by sonication.
We report the microwave assisted synthesis of a bidimensional (2D) MOF of formula [Dy(MeCOO)(PhCOO)(2)](n) (1) and its magnetically diluted analogue [La0.9Dy0.1(MeCOO)(PhCOO)(2)] (1 d). 1 is a 2D material with single-ion-magnet (SIM) behaviour and 1 d is a multifunctional, magnetic and luminescent 2D material. 1 can be exfoliated into stable nanosheets by sonication.
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