期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 21, 页码 11740-11744出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202100810
关键词
bis-organometallic; chain-walking; Ni catalysis; olefin functionalization
资金
- ICIQ
- FEDER/MICIU [AEI/PGC2018-096839-B-100]
- MINECO
- European Union's Horizon 2020 under the Marie Curie PREBIST grant [754558]
A catalytic 1,1-difunctionalization of unactivated olefins is described for the synthesis of sp(3) bis-organometallic B,B(Si)-reagents. The protocol features exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, providing a new platform for accessing sp(3) bis-organometallics.
A catalytic 1,1-difunctionalization of unactivated olefins en route to sp(3) bis-organometallic B,B(Si)-reagents is described. The protocol is characterized by exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, constituting a new platform to access sp(3) bis-organometallics.
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