期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 37, 页码 20144-20165出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202100778
关键词
applications; catalysis; fatty acids; renewable resources; synthesis
资金
- Deutsche Forschungsgemeinschaft (DFG)
- Bundesministerium fur Bildung und Forschung (BMBF)
- Bundesministerium fur Ernahrung und Landwirtschaft (BMEL)
- European Union
- Fonds der Chemischen Industrie (FCI)
- Projekt DEAL
Oils and fats of vegetable and animal origin are important renewable feedstock for the chemical industry, with their industrial use increasing significantly in the past decade. Remarkable achievements in oleochemistry include reduction of fatty esters, selective oxidation of double bonds, synthesis of alkyl-branched compounds, and applications in the synthesis of polymeric materials.
Oils and fats of vegetable and animal origin remain an important renewable feedstock for the chemical industry. Their industrial use has increased during the last 10 years from 31 to 51 million tonnes annually. Remarkable achievements made in the field of oleochemistry in this timeframe are summarized herein, including the reduction of fatty esters to ethers, the selective oxidation and oxidative cleavage of C-C double bonds, the synthesis of alkyl-branched fatty compounds, the isomerizing hydroformylation and alkoxycarboxylation, and olefin metathesis. The use of oleochemicals for the synthesis of a great variety of polymeric materials has increased tremendously, too. In addition to lipases and phospholipases, other enzymes have found their way into biocatalytic oleochemistry. Important achievements have also generated new oil qualities in existing crop plants or by using microorganisms optimized by metabolic engineering.
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