期刊
ADVANCED FUNCTIONAL MATERIALS
卷 31, 期 16, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202010291
关键词
ion co‐ migration; lithium‐ ion battery; Ni; Li antisite; Ni‐ rich cathode; scanning transmission electron microscopy; surface reconstruction
类别
资金
- Beijing Natural Science Foundation [Z190010]
- National Key R&D Program of China [2019YFA0308500]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB07030200]
- National Natural Science Foundation of China [51991344, 52025025, 52072400]
The study reports that surface reconstruction induced by specific antisites can suppress the outward migration of transition metals and oxygen ions, achieving a stable surface structure for layered oxide cathodes of lithium-ion batteries.
Loss of active materials is a critical problem of layered oxide cathodes for lithium-ion batteries and undermines their long-term electrochemical performance. However, the atomic-scale outward migration mechanism of transition metals and oxygen remains elusive due to a highly localized environment at surface. Here, the robust surface reconstruction of LiNi0.8Mn0.1Co0.1O2 (NMC811) induced by artificially introduced Ni/Li antisites is reported. Using scanning transmission electron microscopy, the outward co-migration process of nickel and oxygen ions is directly revealed at the atomic scale, finally resulting in a stable surface structure. The robust nature of this surface structure originates from the strong linear superexchange interaction between subsurface Ni-Li and surface Ni as supported by first-principles calculations. An idealized subsurface structure with 13 Ni-Li is designed to suppress the outward migration of transition metal and oxygen ions and provide a universal lattice-coherent surface protection strategy for layered lithium transition metal oxide cathodes.
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