期刊
ELECTROCHIMICA ACTA
卷 209, 期 -, 页码 691-699出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.05.092
关键词
lithium-sulfur battery; carbon fiber cloth; interlayer; long cycle stability; good rate capability
资金
- National Natural Science Foundation of China [21376001]
- Beijing Higher Education Young Elite Teacher Project [YETP1205]
Significant efforts have been made to eliminate the shuttle effect created by the surface modification of separator or by adding interlayers. However, much of the research so far requires elaborate and costly material processing steps that did not necessarily result in substantially improved cell performances. In this contribution, a three-dimensional carbon fiber cloth (CFC) is placed between the separator and the sulfur cathode to accommodate and capture the soluble polysulfide intermediates. The cells with this interlayer show an initial discharge capacity of 6.89 mAh cm(-2), which remains substantial after 100 cycles at 1C (6.69 mAh cm(-2)). CFC interlayers provide an efficient and cost effective route for developing promising lithium-sulfur batteries with long cycle stability and good rate capability. (C) 2016 Elsevier Ltd. All rights reserved.
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