Atomically Dispersed Indium Sites for Selective CO2 Electroreduction to Formic Acid

An atomically dispersed structure is attractive for electrochemically converting carbon dioxide (CO2) to fuels and feedstock due to its unique properties and activity. Most single-atom electrocatalysts are reported to reduce CO2 to carbon monoxide (CO). Herein, we develop atomically dispersed indium (In) on a nitrogen-doped carbon skeleton (In-N-C) as an efficient catalyst to produce formic acid/formate in aqueous media, reaching a turnover frequency as high as 26771 h(-1) at -0.99 V relative to a reversible hydrogen electrode (RHE). Electrochemical measurements show that trace amounts of In loaded on the carbon matrix significantly improve the electrocatalytic behavior for the CO2 reduction reaction, outperforming conventional metallic In catalysts. Further experiments and density functional theory (DFT) calculations reveal that the formation of intermediate *OCHO on isolated In sites plays a pivotal role in the efficiency of the CO2-to-formate process, which has a lower energy barrier than that on metallic In.

Automated summary

A novel atomically dispersed indium catalyst has been developed for efficiently producing formic acid/formate in aqueous media, outperforming conventional metallic In catalysts. The formation of the intermediate *OCHO on isolated In sites plays a pivotal role in the efficiency of the CO2-to-formate process, with a lower energy barrier compared to metallic In.