期刊
ACS APPLIED MATERIALS & INTERFACES
卷 13, 期 8, 页码 9955-9964出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c21065
关键词
lithium-selenium battery; three-dimensional; ordered; interconnected; photonic crystal; Se-rich composites
资金
- National Natural Science Foundation of China [51673115, 51373097, YG2016MS19]
By using a three-dimensional nitrogen-doped carbon photonic crystal as the host material and introducing a small amount of sulfur to reduce the molecular mass while maintaining high electronic conductivity, Se-rich Se1-xSx@NCPC composites exhibit excellent electrochemical performance in Li-Se batteries.
Lithium-selenium (Li-Se) batteries suffer from the problems of polyselenides dissolution and volume expansion of active materials during the charge/discharge process. Moreover, the heavy atomic mass of selenium atoms limits the capacitive property of a Li-Se battery. Porous materials as the host for selenium particles reported by previous research studies are often disordered in pore structure and nonuniform in pore size. Herein, we report that a three-dimensional (3D) nitrogen-doped carbon photonic crystal (NCPC) with an ordered, interconnected structure was synthesized via a simple method to be the host of active materials. In addition, we prepared a Se-rich Se1-xSx by introducing a small amount of sulfur into a selenium ring to reduce the molecular mass but still keep the high electronic conductivity. As cathodes for a Li-Se battery, amorphous Se-rich Se1-xSx@NCPC composites exhibited high electrochemical performance with a specific capacity of 692 mA h at 0.1 Ag1-, an excellent rate capability of 526 mA h g(-1 )at 3 Ag1-, and an outstanding cycling property with an ultralow decay rate of 0.0132% per cycle at 0.6 Ag1- over 1000 cycles. Moreover, the pouch cell of Se1-xSx @NCPC composites also showed a good property with an energy of 253 Wh kg(-1) at 0.1 Ag1- and an outstanding rate energy of 192 Wh kg(-1) at 1.5 Ag1-, manifesting great potential in practical application.
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