CNTs/LiV3O8/Y2O3 Composites with Enhanced Electrochemical Performances as Cathode Materials for Rechargeable Solid-State Lithium Metal Batteries

Solid-state lithium metal battery (SSLMB) is regarded as a safer energy storage system compared to the liquid one. The performance of the SSLMB depends on the cathode performance and the side reactions derived from the interface of the cathode and the electrolyte, which becomes much severe at high temperatures. Herein, we carried out a facile spray-drying route to prepare a CNTs/LiV3O8/Y2O3 (M-LVO-Y) composite. The synthesized cathode material exhibits an outstanding Li+ storage performance with a high reversible capacity of 279.9 mA h g(-1) at 0.05 A g(-1), excellent power capability (182.5 mA h g(-1) at 2 A g(-1)), and a long cycle lifespan of 500 cycles with a capacity retention of 66.5% at a current density of 1 A g(-1). The fabricated rechargeable solid-state Li/M-LVO-Y-2 lithium metal battery (LMB) with a poly(ethylene oxide) (PEO)-based solid polymer electrolyte (SPE) achieves a high discharge capacity of 302.1 mA h g(-1) at 0.05 A g(-1) and a stable cycling performance with the highest capacity of 72.1% after 100 cycles at 0.2 A g(-1) and 80 degrees C. The above battery performance demonstrates that SSLMBs with the CNTs/LiV3O8/Y2O3 cathode and the PEO-based SPE film can provide high energy density and are suitable for applying in a high-temperature environment.

Automated summary

The CNTs/LiV3O8/Y2O3 cathode composite synthesized by spray-drying shows excellent Li+ storage performance in SSLMBs, with high reversible capacity, power capability, and cycle lifespan. The rechargeable solid-state Li/M-LVO-Y-2 LMB with PEO-based SPE film achieves high discharge capacity and stable cycling performance in high-temperature environments.