期刊
ELECTROCHIMICA ACTA
卷 190, 期 -, 页码 538-547出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.01.011
关键词
Poly(diallyldimethylammonium chloride); Few-layer molybdenum disulfide; Graphene; Electrochemical lithium storage; Hydrothermal route
资金
- International Science and Technology Cooperation Program of China [2012DFG42100]
- Natural Science Foundation of China [21173190, 21473156]
- A*STAR Project [1220203049 (R279-000-370-305)]
The MoS2/graphene composites were synthesized by a hydrothermal route in the presence of graphene oxide sheets with assistance from poly(diallyldimethylammonium chloride) (PDDA). The results of characterizations show that the MoS2/graphene composites exhibit a graphene-like morphology with interconnected network, in which single- or few-layer MoS2 sheets are homogenously dispersed and well anchored on the graphene surface. The robust heterostructure and morphology of MoS2/graphene composites can not only provide more sites and channels for lithium ion accommodation and diffusion, but also facilitate electrolyte access. The heterostructure also maximizes the synergistic effects between MoS2 and graphene. Therefore, MoS2/graphene composites exhibit significantly improved electrochemical performances for reversible lithium storage. In particular, the MoS2/graphene composite prepared with monomer concentration of PDDA being 0.02 mol L (1) exhibits a reversible capacity of 1100 mA h g (1) with enhanced rate capability. The reversible capacity of 856 mA h g (1) after 900 cycles at 500 mA g (1) can be remained, indicating its excellent cyclic stability. (C) 2016 Elsevier Ltd. All rights reserved.
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