期刊
MATERIALS TODAY ENERGY
卷 18, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.mtener.2020.100509
关键词
(NH4)(x)V2O5 center dot nH(2)O; Intercalation; Zn-ion battery; Capacity; Electrochemical properties
资金
- National Natural Science Foundation of China [21771030]
- Natural Science Foundation of Liaoning Province [2020-MS-113]
- Fundamental Research Funds for the Central Universities [DUT18RC(6)008]
Considering many factors, including environmental protection, high cost, and limited resource, aqueous rechargeable Zn-ion batteries (ARZIBs) are expected to be a new next-generation grid to replace Li-ion batteries. The open layered framework of (metal ions intercalated) hydrated vanadium pentoxides is conducive to the transfer and diffusion of zinc ions, making this kind of material a promising cathode material. In this work, ammonium ion (NH4+) intercalated hydrated vanadium pentoxide [(NH4)xV(2)O(5)center dot nH(2)O, abbreviated as NVOH] is prepared by a comparatively low-temperature synthesis and developed as a cathode material for ARZIBs. The influence of different types and concentrations of zinc salt electrolytes on the electrochemical performance is first studied, demonstrating that 3 M Zn(CF3SO3)(2) shows the most excellent performance. The Zn//NVOH battery delivers superior electrochemical reversibility, a high specific capacity (372 mAh.g(-1) at 0.1 A.g(-1)), a preeminent energy density (273 Wh.kg(-1) at 155 W.kg(-1)), and a long lifespan cycling performance (175 mAh.g(-1) after 2,000 cycles at 5 A.g(-1)), which is superior to or comparable to most up-to-the-minute V-based materials applied to ARZIBs. The intercalation reversibility of zinc ion is proved during the electrochemical reaction by various characteristic measurements. This work not only provides a low-temperature hydrothermal synthesis route (100 degrees C) for NVOH but also demonstrates that it can be a promising supplement for zinc ion batteries or other portable battery devices. (C) 2020 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据